Grain Fumigants Market Size and Share

Grain Fumigants Market Summary
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Grain Fumigants Market Analysis by Mordor Intelligence

The grain fumigants market size reached USD 1.45 billion in 2025 and is on course to climb to USD 1.93 billion by 2030, advancing at a 5.9% CAGR over the forecast period. Expansion rests on the rising scale of global grain output, stricter phytosanitary rules, and continuous upgrades in storage infrastructure, especially across Asia-Pacific. Ongoing regulatory phase-outs of methyl bromide, coupled with persistent insect resistance concerns, are pushing operators toward next-generation phosphine blends and emerging carbon dioxide systems. Technology advancements such as (IOT) Internet-of-Things gas monitoring devices are helping large facilities lower labor costs and prove compliance. Moderate market concentration leaves room for both multinational suppliers seeking scale efficiencies and regional specialists solving crop or climate-specific challenges in the grain fumigants market.

Key Report Takeaways

  • By chemical type, aluminum phosphide led with 41% of the grain fumigants market share in 2024, while carbon dioxide is projected to expand at an 8% CAGR to 2030. 
  • By form, solid tablets and pellets accounted for 57% share of the grain fumigants market size in 2024, and gas formulations are advancing at a 7% CAGR through 2030. 
  • By end-use facility, commercial elevators held a 38% share of the grain fumigants market in 2024, whereas shipping containers and barges posted the fastest 8.2% CAGR to 2030.
  • By crop, wheat retained 40% of the grain fumigants market share in 2024, and rice fumigation is forecast to grow at a 7% CAGR through 2030.
  • By region, Asia-Pacific dominated with 36% of the grain fumigants market in 2024, and Africa is projected to grow at a CAGR of 7.2% through 2030.

Segment Analysis

By Chemical Type: Aluminum Phosphide Dominance Faces Carbon Dioxide Challenge

Aluminum phosphide held a 41% share of the grain fumigants market size in 2024. This domination is due to its low cost per treated ton and compatibility with existing silo protocols. Stable demand persists across wheat and corn warehouses, yet sales growth is modest as usage rates plateau. Carbon dioxide is projected to grow at an 8% CAGR through 2030, driven by organic certification programs and customer pressure to cut synthetic residues. In Europe, CO₂ use jumped after a major malt exporter adopted Cocoon inflatables that double as both hermetic liners and fumigation chambers.

Phosphine gas remains essential for emergency knock-down treatments where infestations threaten export timelines, while magnesium phosphide serves geographies with aluminum-based import restrictions. Sulfuryl fluoride’s trajectory is mixed as structural fumigators value its penetrative power, but food-contact limitations dampen growth prospects. Regulatory scrutiny is pushing suppliers to invest in combination products that pair phosphine with carbon dioxide to achieve quicker kill rates at lower dosages, an innovation likely to reshape the chemical mix in the grain fumigants market.

Grain Fumigants Market: Market Share by Chemical Type
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By Form: Solid Formulations Lead While Gaseous Applications Gain Momentum

Solid tablets and pellets dominated with a 57% share of the grain fumigants market size in 2024, as elevator managers favor their simple handling and long shelf life. No special compressors or hoses are needed, so capital outlay stays minimal. That convenience underpins steady re-order cycles in mature markets. Gas cylinders and on-site generators, though, will expand 7% CAGR because controlled-atmosphere shipping demands precise dosage tied to voyage length. IoT-equipped valves now regulate gas flow automatically, mitigating the historic safety concerns that had capped adoption.

Liquid formulations retain a minor niche for damp storage scenarios where solids degrade. Across all forms, training content is evolving with suppliers embedding QR-linked micro-videos on labels, guiding applicators on dosage math and safety checkpoints. The format shift toward gases is therefore not merely chemical but also digital, supporting broader productivity gains inside the grain fumigants market.

By End-Use Facility: Commercial Elevators Anchor Market While Shipping Applications Surge

Commercial grain elevators captured 38% of grain fuimgants market share in 2024 because they sit at the intersection of farm supply and export channels; continuous loading cycles drive year-round treatment schedules. These high-volume hubs favor aluminum phosphide tablets for cost control, but leading chains are installing central dosing manifolds for phosphine gas to streamline large bunker fumigations. Shipping containers and barges, although smaller in base, will outpace all other facilities at 8.2% CAGR as maritime grain traffic rises on Asia-Pacific to Middle East routes. The shift is amplified by canal disruptions that have lengthened transit times, increasing infestation risk.

On-farm silos show moderate growth as mid-sized growers modernize, while warehouse and transit depots capture spillover demand tied to multimodal logistics. Each facility type thus maps to distinct product-service packages, forcing suppliers to segment their portfolios accordingly within the grain fumigants market.

Grain Fumigants Market: Market Share by End-Use Facility
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By Crop Type: Wheat Applications Dominate While Rice Storage Drives Growth

Wheat held about 40% of grain fumigants market share in 2024, a testament to its global acreage and the multi-month storage windows demanded by milling schedules. The segment’s maturity supports incremental upgrades like sensor-guided fumigation. Rice, conversely, is projected to post 7% CAGR through 2030 as Asia-Pacific exporters double warehouse capacities to meet rising African demand. 

High-humidity storage creates ideal conditions for the lesser grain borer, accelerating adoption of phosphine plus carbon dioxide blends. Corn remains influential across the Americas, where ethanol and feed markets sustain year-round inventory buffers. Specialty grains such as sorghum, millet, and quinoa show smaller but premium margins, creating niches for customized fumigation protocols in the grain fumigants market.

Geography Analysis

Asia-Pacific stood as the largest regional contributor, accounting for 36% of the global grain fumigants market share in 2024, which is projected to grow at a CAGR of 5.4% through 2030. Vast wheat and rice production belts and accelerating warehouse construction across China, India, and Vietnam support this growth. China’s regulatory overhaul in late 2024 streamlined biopesticide registration yet retained phosphide approvals, keeping demand robust. India approved 416 new products in the first half of 2024, signaling an active compliance environment that favors certified suppliers. Urban migration drives centralized grain storage, with multi-silo parks near port clusters demanding integrated fumigation and monitoring suites. 

Africa is the fastest-growing region at 7.2% CAGR through 2030. Post-harvest cereal losses of USD 4 billion annually galvanized donor-funded programs that co-finance modern silos and promote professional fumigation. Nigeria’s grain merchant associations now host mandatory certification workshops, and Ghana’s acceptance of CO₂ hermetic liners for organic export lots is pulling in technology providers. Knowledge gaps persist, but rising food-security stakes ensure sustained policy attention. 

North America and Europe feature mature but innovation-driven landscapes, expanding at 3.8% and 4.4% CAGR, respectively. EPA’s ongoing registration reviews tighten exposure guidelines, compelling operators to adopt gas-monitoring IoT gear. Europe’s energy-price volatility also steers some elevators toward low-temperature controlled atmospheres to save on aeration costs. South America will post a 6.3% CAGR on the back of Brazil’s USD 88.2 billion 2024/25 farm credit line, which pairs loan disbursements with post-harvest infrastructure targets. Across all regions, the keyword is differentiation: suppliers must tailor product mixes to local residue regulations, crop profiles, and infrastructure maturity to win in the grain fumigants market.

Grain Fumigants Market CAGR (%), Growth Rate by Region
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Competitive Landscape

In 2024, the global grain fumigants market exhibited moderate concentration, with the top five players accounting for a significant portion of total revenue. UPL Limited stood out, supported by its vertically integrated capabilities in active-ingredient synthesis and an extensive distribution footprint spanning 130 countries. Detia Degesch Group maintained a strong position due to its long-standing expertise in aluminum phosphide and a physical presence across all major grain-producing regions. 

Douglas Products and Syensqo built competitive advantages through their respective patent portfolios in phosphine and sulfuryl fluoride technologies, while Cardinal Professional Products maintained a solid foothold by focusing on service coverage throughout North America. Strategic developments in 2024–2025 reflected trends in horizontal expansion and digital innovation. Ecotec (Rentokil Initial Plc) acquired HiCare in India to boost service density and broaden its fumigation offerings to commercial grain millers. GrainPro gained approval from India's DPPQ&S for its CO₂-based Cocoon system, reinforcing its position at the forefront of eco-friendly fumigation solutions. 

UPL and Syensqo collaborated on the development of sensor-integrated tablets linked to mobile dashboards, streamlining compliance and documentation for HACCP audits. As regulatory demands grow more complex, competitive pressures are expected to intensify. Nevertheless, smaller regional firms can still succeed by focusing on niche crops or offering monitoring technologies that enhance the value propositions of larger multinational chemical portfolios.

Grain Fumigants Industry Leaders

  1. UPL Limited

  2. Detia Degesch Group

  3. Ecotec (Rentokil Initial plc)

  4. Syensqo

  5. Douglas Products

  6. *Disclaimer: Major Players sorted in no particular order
Grain Fumigants Market Concentration
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Recent Industry Developments

  • February 2025: The Environmental Protection Agency (EPA) approved an amendment to the ProFume (sulfuryl fluoride) label for use in food-handling facilities and grain warehouses, adding stricter stewardship and site-specific fumigation logging provisions. This enhances compliance and traceability in commercial grain fumigation.
  • November 2024: Detia Degesch Group established a dedicated Organic Division to focus on green fumigation solutions and low-residue formulations. This move aligns with increasing global demand for residue-free grain protection and regulatory pressure favoring bio-based or safer alternatives to traditional phosphide fumigants.
  • January 2024: Degesch America, Inc. launched U‑Phos, a cylinderized phosphine fumigant, in the United States. This gas-based alternative to tablets/pellets offers residue-free fumigation and simplified disposal, strengthening its positioning in the grain fumigants market.

Table of Contents for Grain Fumigants Industry Report

1. Introduction

  • 1.1 Study Assumptions and Market Definition
  • 1.2 Scope of the Study

2. Research Methodology

3. Executive Summary

4. Market Landscape

  • 4.1 Market Overview
  • 4.2 Market Drivers
    • 4.2.1 Rising global grain output and larger commercial storage capacities
    • 4.2.2 Stricter phytosanitary import regulations on stored-grain insects
    • 4.2.3 Regulatory phase-out of methyl bromide accelerates phosphine substitution
    • 4.2.4 Consolidation of grain handling infrastructure in Asia-Pacific
    • 4.2.5 Growth in controlled-atmosphere bulk grain shipping corridors
    • 4.2.6 IoT-enabled real-time gas monitoring lowers fumigation cost and risk
  • 4.3 Market Restraints
    • 4.3.1 Increasing insect resistance to phosphine
    • 4.3.2 High toxicity concerns and tightening worker-safety regulations
    • 4.3.3 Rapid adoption of hermetic storage systems in smallholder settings
    • 4.3.4 Carbon-footprint scrutiny on sulfuryl fluoride emissions
  • 4.4 Regulatory Landscape
  • 4.5 Technological Outlook
  • 4.6 Porter's Five Forces Analysis
    • 4.6.1 Threat of New Entrants
    • 4.6.2 Bargaining Power of Suppliers
    • 4.6.3 Bargaining Power of Buyers
    • 4.6.4 Threat of Substitutes
    • 4.6.5 Competitive Rivalry

5. Market Size and Growth Forecasts (Value)

  • 5.1 By Chemical Type
    • 5.1.1 Aluminum Phosphide
    • 5.1.2 Magnesium Phosphide
    • 5.1.3 Phosphine Gas
    • 5.1.4 Sulfuryl Fluoride
    • 5.1.5 Carbon Dioxide
    • 5.1.6 Others
  • 5.2 By Form
    • 5.2.1 Solid Tablets and Pellets
    • 5.2.2 Liquid
    • 5.2.3 Gas
  • 5.3 By End-Use Facility
    • 5.3.1 Commercial Grain Elevators
    • 5.3.2 On-farm Silos
    • 5.3.3 Shipping Containers and Barges
    • 5.3.4 Warehouse and Transit Storage
  • 5.4 By Crop Type
    • 5.4.1 Wheat
    • 5.4.2 Corn
    • 5.4.3 Rice
    • 5.4.4 Sorghum and Millet
    • 5.4.5 Others
  • 5.5 By Region
    • 5.5.1 North America
    • 5.5.1.1 United States
    • 5.5.1.2 Canada
    • 5.5.1.3 Rest of North America
    • 5.5.2 South America
    • 5.5.2.1 Brazil
    • 5.5.2.2 Argentina
    • 5.5.2.3 Rest of South America
    • 5.5.3 Europe
    • 5.5.3.1 Germany
    • 5.5.3.2 France
    • 5.5.3.3 United Kingdom
    • 5.5.3.4 Italy
    • 5.5.3.5 Spain
    • 5.5.3.6 Russia
    • 5.5.3.7 Rest of Europe
    • 5.5.4 Asia-Pacific
    • 5.5.4.1 China
    • 5.5.4.2 India
    • 5.5.4.3 Japan
    • 5.5.4.4 Australia
    • 5.5.4.5 South Korea
    • 5.5.4.6 Rest of Asia-Pacific
    • 5.5.5 Middle East
    • 5.5.5.1 Saudi Arabia
    • 5.5.5.2 Turkey
    • 5.5.5.3 Rest of Middle East
    • 5.5.6 Africa
    • 5.5.6.1 South Africa
    • 5.5.6.2 Egypt
    • 5.5.6.3 Rest of Africa

6. Competitive Landscape

  • 6.1 Market Concentration
  • 6.2 Strategic Moves
  • 6.3 Market Share Analysis
  • 6.4 Company Profiles (includes Global level Overview, Market level overview, Core Segments, Financials as available, Strategic Information, Market Rank/Share for key companies, Products and Services, and Recent Developments)
    • 6.4.1 UPL Limited
    • 6.4.2 Detia Degesch Group
    • 6.4.3 Douglas Products
    • 6.4.4 Syensqo
    • 6.4.5 Royal Agro Organics
    • 6.4.6 Cardinal Professional Products
    • 6.4.7 Ecotec (Rentokil Initial plc)
    • 6.4.8 Agrofena
    • 6.4.9 POMAIS Agriculture (Shijiazhuang Pomais Technology Co., Ltd.)
    • 6.4.10 Rollins, Inc.

7. Market Opportunities and Future Outlook

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Global Grain Fumigants Market Report Scope

By Chemical Type
Aluminum Phosphide
Magnesium Phosphide
Phosphine Gas
Sulfuryl Fluoride
Carbon Dioxide
Others
By Form
Solid Tablets and Pellets
Liquid
Gas
By End-Use Facility
Commercial Grain Elevators
On-farm Silos
Shipping Containers and Barges
Warehouse and Transit Storage
By Crop Type
Wheat
Corn
Rice
Sorghum and Millet
Others
By Region
North America United States
Canada
Rest of North America
South America Brazil
Argentina
Rest of South America
Europe Germany
France
United Kingdom
Italy
Spain
Russia
Rest of Europe
Asia-Pacific China
India
Japan
Australia
South Korea
Rest of Asia-Pacific
Middle East Saudi Arabia
Turkey
Rest of Middle East
Africa South Africa
Egypt
Rest of Africa
By Chemical Type Aluminum Phosphide
Magnesium Phosphide
Phosphine Gas
Sulfuryl Fluoride
Carbon Dioxide
Others
By Form Solid Tablets and Pellets
Liquid
Gas
By End-Use Facility Commercial Grain Elevators
On-farm Silos
Shipping Containers and Barges
Warehouse and Transit Storage
By Crop Type Wheat
Corn
Rice
Sorghum and Millet
Others
By Region North America United States
Canada
Rest of North America
South America Brazil
Argentina
Rest of South America
Europe Germany
France
United Kingdom
Italy
Spain
Russia
Rest of Europe
Asia-Pacific China
India
Japan
Australia
South Korea
Rest of Asia-Pacific
Middle East Saudi Arabia
Turkey
Rest of Middle East
Africa South Africa
Egypt
Rest of Africa
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Key Questions Answered in the Report

What is the current size of the grain fumigants market?

The market stands at USD 1.45 billion in 2025 and is projected to reach USD 1.93 billion by 2030.

Which chemical type holds the largest market share?

Aluminum phosphide leads with 41% of grain fumigants market share in 2024.

Why is Asia-Pacific the dominant regional market?

The region combines massive wheat and rice output with rapid modernization of storage facilities that require professional fumigation services.

How do regulations influence market growth?

Stricter phytosanitary import rules and the phase-out of methyl bromide compel exporters to adopt certified phosphine-based or CO₂ systems, sustaining demand.

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